Isomerization Process Overview | Delayed Coking Process Overview

Isomerization converts n-butane, n-pentane and n-hexane into their respective iso-paraffins of substantially higher octane number. The straight-chain paraffins are converted to their branched-chain counterparts whose component atoms are the same but are arranged in a different geometric structure. Isomerization is important for the conversion of n-butane into iso-butane, to provide additional feedstock for alkylation units, and the conversion of normal pentanes and hexanes into higher branched isomers for gasoline blending. Isomerization is similar to catalytic reforming in that the hydrocarbon molecules are rearranged, but unlike catalytic reforming, isomerization just converts normal paraffins to iso-paraffins.

Isomerization Process Overview | Delayed Coking Process Overview

There are two distinct isomerization processes, butane (C4) and pentane/hexane (C5/C6). Butane isomerization produces feedstock for alkylation. Aluminum chloride catalyst plus hydrogen chloride are universally used for the low-temperature processes. Platinum or another metal catalyst is used for the higher-temperature processes. In a typical low-temperature process, the feed to the isomerization plant is n-butane or mixed butanes mixed with hydrogen (to inhibit olefin formation) and passed to the reactor at 230°-340°F and 200-300 psi. Hydrogen is flashed off in a high-pressure separator and the hydrogen chloride removed in a stripper column. The resultant butane mixture is sent to a fractionator (de-iso-butanizer) to separate n-butane from the iso-butane product.

Pentane/hexane isomerization increases the octane number of the light gasoline components n-pentane and n-hexane, which are found in abundance in straight-run gasoline. In a typical C5/C6 isomerization process, dried and desulfurized feedstock is mixed with a small amount of organic chloride and recycled hydrogen, and then heated to reactor temperature. It is then passed over supported-metal catalyst in the first reactor where benzene and olefins are hydrogenated.

The feed next goes to the isomerization reactor where the paraffins are catalytically isomerized to iso-paraffins. The reactor effluent is then cooled and subsequently separated in the product separator into two streams: a liquid product (isomerate) and a recycle hydrogen-gas stream. The isomerate is washed (caustic and water), acid stripped, and stabilized before going to storage.

Schematic of C4 Isomerization

Schematic of C4 Isomerization

Isomerization process targeting step include drawing a boundary around the facility.
Heat in and out, directly, and/or indirectly through steam consumption and/or generation,
water production and/or generation, power consumption and/or generation are among the
plant’s boundary are all identified.

Again heat integration between feed and product is common in such facilities; integration
between reaction and separation section and between distillation columns are highly
recommended to achieve lower energy consummation targets. Complete pinch technology
application for such plants will be included in later versions of this manual.


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